ChemPubSoc Europe is an organization of 16 European chemical societies, founded in the late 1990s as a consequence of the amalgamation of many chemical journals owned by national chemical societies into a number of high-quality European journals.
ChemPubSoc Europe's journals, all published with Wiley-VCH, are: Chemistry—A European Journal, European Journal of Organic Chemistry, European Journal of Inorganic Chemistry, ChemBioChem, ChemPhysChem, ChemMedChem, ChemSusChem, ChemCatChem, ChemPlusChem, ChemElectroChem, ChemistryOpen, and ChemViews, the ChemPubSoc Europe e-zine. They replaced 16 traditional national chemistry journals.
The participating societies share a commitment to scientific excellence, to publishing ethics, and to the highest standards in publication, which are the basis for the success of the ChemPubSoc Europe journals.
ChemPubSoc Europe and its Asian sister organization, the Asian Chemical Editorial Society (ACES), mutually support each other in the publication of their journals Chemistry—A European Journal, Chemistry—An Asian Journal, and ChemSusChem.
© Wiley-VCH 2009–2013
The latest impact factors for the ChemPubSoc Europe journals are as follows (2013):
|Chemistry A—European Journal||5.696|
|European Journal of Organic / Inorganic Chemistry||3.145 / 2.965|
|ChemPhysChem / ChemElectroChem||3.360 / n/a|
|ChemBioChem / ChemMedChem||3.060 / 3.046|
|ChemSusChem / ChemCatChem||7.117 / 5.044|
|ChemPlusChem / ChemistryOpen||3.242 / 2.938|
An economical and scalable synthesis of rac-(Z)-β-santalol is accomplished. The key coupling step is based on a Scriabine-inspired reaction of a dienyl diacetate substrate and an alkene. The total synthesis is achieved in five steps (longest linear sequence) in 19 % overall yield from cyclopentadiene; Cp* = C5Me5, cod = 1,5-cyclooctadiene, Tf = trifluoromethylsulfonyl.
Anthony A. Birkbeck, Xavier Marquet, Pascal Millet, Hervé Pamingle
Eur. J. Org. Chem., October 29, 2014, DOI: 10.1002/ejoc.201403219. Read article.
A series of nonsymmetrical Mitsunobu reagents that avoid byproduct separation problems in this useful reaction are reported. They are readily prepared by a one-pot sequence from inexpensive, commercially available materials and are shown to possess activity that is parallel to that of diethyl azodicarboxylate/diisopropyl azodicarboxylate in a wide range of synthetic transformations.
Daniel P. Furkert, Benjamin Breitenbach, Ludovic Juen, Ina Sroka, Mathilde Pantin, Margaret A. Brimble
Eur. J. Org. Chem., October 29, 2014, DOI: 10.1002/ejoc.201403152. Read article.
The rate of electrocyclic ring-closure of vinylheptafulvene (VHF) to dihydroazulene (DHA) has been studied for a series of compounds bearing a rate-enhancing nitrophenyl group connected to the VHF through either a linear or cross-conjugated bridge. The photoactive DHA compounds were prepared by metal-catalyzed coupling reactions and converted into the VHFs by irradiation.
Kasper Fjelbye, Trine Nørgaard Christensen, Martyn Jevric, Søren Lindbæk Broman, Anne Ugleholdt Petersen, Anders Kadziola, Mogens Brøndsted Nielsen
Eur. J. Org. Chem., October 29, 2014, DOI: 10.1002/ejoc.201403117. Read article.
Under a co-catalytic AuI/CuI system, tandem 1,3-acyloxy migration/trifluoromethylation reactions of propargyl esters give α-trifluoromethyl enones with excellent stereoselectivity and in moderate yields.
Yun-Long Ji, Jin-Hong Lin, Ji-Chang Xiao, Yu-Cheng Gu
Eur. J. Org. Chem., October 29, 2014, DOI: 10.1002/ejoc.201403115. Read article.
Enantioselective allylation and crotylation of tert-butyldimethylsilyl (TBS) protected vanillin proceeds with high asymmetric induction (92–96 % ee) by using different catalytic systems. The product of crotylation is converted into the unnatural diastereoisomer of a recently isolated lignan derivative.
Timothée Cadart, Petr Koukal, Martin Kotora
Eur. J. Org. Chem., October 29, 2014, DOI: 10.1002/ejoc.201403094. Read article.
(–)-Isopulegol undergoes Prins–arylthiolation with aldehydes and cyclohexanone in the presence of HBF4·OEt2 to generate a library of 4-arylthio-octahydro-2H-chromene derivatives in good to excellent yields with moderate to high cis selectivity at ambient temperature in CH2Cl2. HBF4·OEt2 as a catalyst outshines CF3CO2H, which is generally used in excess amounts in Prins cyclization and domino Prins–arylthiolation reactions.
Barnali Sarmah, Gakul Baishya, Rajani K. Baruah
Eur. J. Org. Chem., October 29, 2014, DOI: 10.1002/ejoc.201403080. Read article.
An efficient process for the enantioselective synthesis of optically active 3,4-dihydrothiacarbazol-2(9H)-one derivatives has been developed The cascade Michael addition/thiolysis reactions of 9-methylindoline-2-thiones and N-alkenoylphthalimides were promoted by a chiral bifunctional squaramide catalyst to give the desired products in acceptable yields with 54–98 % ee.
Shanren Chen, Jianping Pan, Youming Wang, Zhenghong Zhou
Eur. J. Org. Chem., October 29, 2014, DOI: 10.1002/ejoc.201403078. Read article.
Isoxazolinofullerenes have been synthesised directly from activated nitro compounds by a catalytic process (DABCO or NMP/[Cu]). The protocol is simple, versatile and tolerant towards diverse functional groups. A mechanism is proposed to explain both this condensation and the known addition with nitroethane in excess base.
Giacomo Biagiotti, Stefano Cicchi, Francesco De Sarlo, Fabrizio Machetti
Eur. J. Org. Chem., October 29, 2014, DOI: 10.1002/ejoc.201402990. Read article.
The ruthenium-catalyzed alkenylation of arenes with unsaturated alkanes has been achieved by triazole-directed C–H activation. Dialkenylated arenes were efficiently produced by this method from internal alkynes as the sole products with high regio- and stereoselectivity.
Xing Guang Li, Kai Liu, Gang Zou, Pei Nian Liu
Eur. J. Org. Chem., October 29, 2014, DOI: 10.1002/ejoc.201402938. Read article.
Craftswerk: A microporous polymer is developed by hypercrosslinking of organosolv lignin, a renewable resource, by Friedel–Crafts chemistry. Further pyrolysis of hypercrosslinked organosolv lignin yields shape-persistent materials with increased capacity for carbon dioxide adsorption. The selectivity towards CO2/N2 mixtures is investigated on the basis of ideal adsorption–solution theory (IAST), indicating excellent selectivity.
Qing Bo Meng, Jens Weber
ChemSusChem, October 29, 2014, DOI: 10.1002/cssc.201402879. Read article.
No template, no surfactant—still good? One-dimensional CuxS (x=1, 2) nanorods have been prepared by using a template- and surfactant-free solvent thermal method, which allows precise control of the composition of the highly crystalline CuxS. The nanorods can be used as anodes in lithium-ion batteries, giving rise to high rate capabilities and electrochemical stability and excellent capacity retention irrespective of the rate used.
Xue Li, Xinyi He, Chunmei Shi, Bo Liu, Yiyong Zhang, Shunqing Wu, Zizong Zhu, Jinbao Zhao
ChemSusChem, October 29, 2014, DOI: 10.1002/cssc.201402862. Read article.
Happy Ester: The oxidative esterification of 5-hydroxymethylfurfural (HMF) and furfural over CoxOy–N@C catalysts is performed using O2 as benign oxidant, obtaining the corresponding esters. High yield and selectivity of 2,5-furandicarboxylic acid methyl and methyl 2-furoate are achieved under optimized conditions.
Jin Deng, Hai-Jie Song, Min-Shu Cui, Yi-Ping Du, Yao Fu
ChemSusChem, October 29, 2014, DOI: 10.1002/cssc.201402843. Read article.
A key building-block: Shelf-stable 3-iodo-Kdo fluoride donors are easily formed from Kdo-glycal esters and they harbor excellent glycosylation properties, combining α-stereospecificity with minimal elimination. Their application is demonstrated in a straightforward regioselective double glycosylation as well as iterative chain elongation leading to branched and linear Chlamydia lipopolysaccharide epitopes (see scheme).
Barbara Pokorny, Paul Kosma
Chem. Eur. J., October 29, 2014, DOI: 10.1002/chem.201405424. Read article.
A novel synthetic approach toward 1,4-disubstituted 1,2,3-triazoles by C-N- and N-N-bond formation has been established under transition-metal-free conditions (see scheme). Complete control of regioselectivity was successfully achieved and anilines, ketones, and N-tosylhydrazines were treated with molecular iodine in one pot to allow the formation of 1,4-disubstitued 1,2,3-triazoles in high yields without the use of azides.
Zhengkai Chen, Qiangqiang Yan, Zhanxiang Liu, Yuhong Zhang
Chem. Eur. J., October 29, 2014, DOI: 10.1002/chem.201405057. Read article.
Responsive twin-disulfide: A twin-disulfide linker bearing two independent disulfide bonds has been developed that shows responses to differing redox environments in a manner that is in remarkable contrast to traditional disulfide bonds (see scheme). The twin-disulfide linker displays an ultrahigh stability at lower concentrations of reducing agent without a significant compromise in the sensitivity of the response to highly reducing environments such as cytoplasm.
Linxiang Zhai, Jingjing Liang, Xiangqun Guo, Yibing Zhao, Chuanliu Wu
Chem. Eur. J., October 29, 2014, DOI: 10.1002/chem.201404909. Read article.
One pair, many adducts: A combined 19F,1H HOESY/DFT methodology to discriminate between adducts held together by halogen bonding (XB) and other noncovalent interactions (non-XB, such as lone pair/π), based on the determination of the XB donors' and acceptors' relative orientation, is reported. Notably, the approach allows also the estimation of the relative concentration of XB and non-XB adducts.
Gianluca Ciancaleoni, Roberta Bertani, Luca Rocchigiani, Paolo Sgarbossa, Cristiano Zuccaccia, Alceo Macchioni
Chem. Eur. J., October 29, 2014, DOI: 10.1002/chem.201404883. Read article.
The long-lived 3LC emissions of tris- cyclometalated PtIV complexes can be tuned from blue to orange through the variation of one the cyclometalating ligands. A combined experimental and DFT/TD-DFT study provides insight into the factors that determine the excited-state properties of this class of compounds.
Fabio Juliá, Gabriel Aullón, Delia Bautista, Pablo González-Herrero
Chem. Eur. J., October 29, 2014, DOI: 10.1002/chem.201404583. Read article.
Pivotal understanding: The chemical and biochemical aspects of lipid A, the endotoxic moiety of the bacterial lipopolysaccharide (LPS) molecule is discussed, as well as its role in innate immunity, from the (bio)synthesis, isolation and characterization to the molecular recognition at the atomic level, which helps to understand the bioactivity of LPS.
Antonio Molinaro, Otto Holst, Flaviana Di Lorenzo, Maire Callaghan, Alessandra Nurisso, Gerardino D'Errico, Alla Zamyatina, Francesco Peri, Rita Berisio, Roman Jerala, Jesús Jiménez-Barbero, Alba Silipo, Sonsoles Martín-Santamaría
Chem. Eur. J., October 29, 2014, DOI: 10.1002/chem.201403923. Read article.
Phantom of the operando: During the methanol-to-olefins process over H-SAPO-34 the reaction pathways leading to the formation of olefins and polyaromatics compete. Based on a unique combined operando approach, a first-order kinetic model is proposed to describe both reactions, revealing comparable activation energies. MCT= Mercury–cadmium–telluride.
Qingyun Qian, Charlotte Vogt, Mohamed Mokhtar, Abdullah M. Asiri, Shaeel A. Al-Thabaiti, Suliman N. Basahel, Javier Ruiz-Martínez, Bert M. Weckhuysen
ChemCatChem, October 29, 2014, DOI: 10.1002/cctc.201402714. Read article.
We plough the surface and scatter: Surface-enhanced Raman spectroscopy can be used to determine the reaction kinetics of surface reactions within self-assembled monolayers. As a proof of principle we have chosen to study the photocatalytic reduction of p-nitrothiophenol. A study of the reaction rate and dilution effects leads to the conclusion that a dimerization must take place as one of the reaction steps.
Evelien M. van Schrojenstein Lantman, Onno L. J. Gijzeman, Arjan J. G. Mank, Bert M. Weckhuysen
ChemCatChem, October 29, 2014, DOI: 10.1002/cctc.201402647. Read article.
Nanorattle catalysis: The photothermal properties of plasmonic nanoparticles are used for photothermal enhancement of the catalytic efficiency of reactions occurring within a hollow palladium nanoparticle containing small solid gold nanospheres in the cavity.
Mahmoud A. Mahmoud, Mostafa A. El-Sayed
ChemCatChem, October 29, 2014, DOI: 10.1002/cctc.201402644. Read article.
Evolution of diolide formation: We propose an evolutionary model in which thioesterases from polyketide biosynthesis are by nature non-selective for the type of chemistry they catalyze, producing a range of metabolites including acids, macrolactones, dimers, and macrodiolides. As one metabolite becomes essential for improving fitness in a particular environment, the thioesterase evolves to enrich for that corresponding reactivity.
Taylor P. A. Hari, Puneet Labana, Meaghan Boileau, Christopher N. Boddy
ChemBioChem, October 29, 2014, DOI: 10.1002/cbic.201402475. Read article.
Glycosylation in macrolactin (MLN) and bacillaene (BAE) biosynthesis: BmmGT1, located in neither the MLN nor the BAE biosynthetic gene cluster, was identified in the genome of Bacillus marinus B-9987. Inactivation of bmmGT1 abolished glycosylated MLN and BAE compounds. However, BmmGT1 exhibited broad substrate specificity, and five novel glycosylated MLNs were generated.
Wen Qin, Yang Liu, Pengfei Ren, Jun Zhang, Huayue Li, Li Tian, Wenli Li
ChemBioChem, October 29, 2014, DOI: 10.1002/cbic.201402384. Read article.
New scaffolds for stapling: A comparison of linear aliphatic dialkynes with aromatic dialkynes for the double-click stapling of p53 peptides demonstrates that the linker scaffold, along with the peptide sequence and staple functionality, can influence the biological activity of stapled peptides in a cellular context.
Yu Heng Lau, Peterson de Andrade, Grahame J. McKenzie, Ashok R. Venkitaraman, David R. Spring
ChemBioChem, October 29, 2014, DOI: 10.1002/cbic.201402374. Read article.